This section is from the book "The English And American Mechanic", by B. Frank Van Cleve. Also available from Amazon: The English And American Mechanic.
This may be effected by the dry and the moist processes; but the deoxidizing agent of the greatest value to the metallurgist is coal in its several varieties, and the derivative materials yielded by its combustion. When coal is burned in a furnace, the first product of combustion may be considered to be carbonic acid gas; but inasmuch as the latter is readily decomposed by permeating ignited pieces of solid carbon (coke) losing a portion of its oxygen, and becoming carbonic acid gas, we may say that the products of the combustion of coal are, firstly, carbonic acid; secondly, carbonic oxide and carbonic acid; and lastly, carbonic oxide alone. The latter, in combination with heat, is a most powerful deoxidizing agent. Were it not for the production in furnaces of carbonic oxide gas - were it necessary that the solid carbon of the coke should be alone the deoxidizing body - then it follows that every particle of the ore to be reduced must be brought into intimate contact with the reducing body; a process involving more care and trouble than are compatible with large metallurgic operations. The reducing agent being a gas, there is no longer a necessity for that intimate mixture of fuel and ore which would otherwise be necessary. Provided that the gaseous results of combustion are placed under circumstances of readily permeating the ore, the necessities of practice are amply subserved. There is great difference as to the amount of heat at which the reduction of different metallic oxides can be effected. The oxides of lead, bismuth, antimony, nickel, cobalt, copper, and iron, require a strong red heat in the furnace, whilst the oxides of manganese, chromium, tin, and zinc, do not lose their oxygen until heated to whiteness.
On a large scale, the reduction of oxides is generally effected by mixing charcoal, together with the oxide to be reduced, in a refractory clay crucible, the charcoal furnishing the carbon necessary to the proper performance of the work. Some use a crucible thickly lined with charcoal, patting in the oxide on the top of the charcoal. It is necessary, however, when using the crucible and charcoal, to use a (lux, say a little borax in powder, stewed on the mixture to accelerate the reduction of the oxide. The borax is generally the first to fuse, and, as the metal is eliminated, seems to purify and cleanse it, as it gathers into a button at the bottom of the crucible. It is all the better if you give the crucible a few sharp taps when you take it off the fire.
Copper Plates or Rods may be covered with a superficial coating of brass by exposing them to the fumes given off by melted zinc at a light temperature. The coated plates or rods can then be rolled into thin sheets; or drawn into wire.
 
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