This section is from the book "Distillation Principles And Processes", by Sydney Young. Also available from Amazon: Distillation Principles And Processes.
The most important of these are benzene, toluene, and the three isomers of xylene. Amount 1-5 per cent.
Containing aromatic hydrocarbons, phenol, cresol and other homologues of phenol. Amount 5-10 per cent.
Containing also high aromatic hydrocarbons, high phenol homologues and naphthalene. Amount 15-25 per cent.
Containing still higher aromatic hydrocarbons and anthracenes. Amount 5-10 per cent.
Amount 50-65 per cent.
The magnitude of the tar-distilling industry in this country can be judged by reference to the following figures, showing the amounts of tar produced and distilled. It seems impossible to obtain complete statistics of any pre-war period, as reliable data were not then kept, and figures relating to these periods can only be estimated roughly. From the Annual Reports on alkali and other works, by the Chief Inspector, are obtained the following data :-
Tar distilled in | 1916. | 1917. | 1918. | 1919. |
Gas and Coke Oven Works } | 1,420,867 | 1,526,209 | 1,510,065 | 1,402,987 |
Other Works | 138,552 | 126,966 | 131,325 | 106,056 |
Total in Tons. | 1,559,419 | 1,653,175 | 1,641,390 | 1,509,043 |
From the Reports for 1916 and 1917 it would appear as though the tar had been obtained from gas works only, but there is no doubt that the figures given should refer to both kinds of works. The Ministry of Munitions collated complete returns of tar produced and distilled during the war and have kindly given the writer the following summaries: Coal Tar and Coke Ovens Tar Distilled, in Tons
1913......... | 1,320,000 |
1914 1915 }Average..................................................... 1916; | 1,376,397 |
1917........................................................................ | 1,574,863 |
Sept. 1917 to Aug. 1918..... | 1,417,919 |
„ ,, (actual production) ................ | 1,523,401 |
For the years prior to Sept. 1917 the total production of tar may be taken as approximately 100,000 tons annually more than that shown as distilled.
For the year Sept. 1917 to Aug. 1918 the sources of tar produced were: -
Gas Works and Produce Plants................. | 949,397 | |
Coke Ovens............................ | ........................... | 558,561 |
Water-gas Plants.............. | ........................... | 15,443 |
Total.................... | 1,523,401 | |
Against these figures estimates of the tar produced have been made, and Dr. Beilby, in an address to the Society of Chemical Industry, 1900, gives such an estimate for the year 1899 as follows: Tar Produced, in Tons
Gas Works............ | ..................................... | 650,000 |
Blast Furnaces............. | .............................. | 150,000 |
Coke Oven..................... | ........................... | 62,000 |
An interesting estimate of the tar produced by all countries of the world for the year 1901 appears in Chemical Discovery and Invention in the Twentieth Century, by Tilden (p. 305) as follows: -
Tons. | |
United Kingdom ...... | . 908,000 |
Germany . . . . . . . . . .. . . . . . .. . . . . . . | . 590,000 |
United States (including water-gas tar). . . . . . . . . . . . | . 272,400 |
France . . . . . . . . . . . . . . . . . . . . . | . 190,680 |
Belgium, Holland, Sweden, Norway, and Denmark . . . . . | . 272,400 |
Austria, Russia, Spain, and other European countries . . . . | . 199,760 |
All other countries...... | . 227,000 |
Total | 2,660,240 |
From this it is evident that the industry in the United Kingdom is more important than in any other country in the world, and, comparing the total of these figures with the tar produced during the most important period of the war, one sees that the United Kingdom produced then very nearly as much as the rest of the world at the beginning of the twentieth century.
 
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